Expand a QuTS 6.0 QTier High-speed RAID 1 array to Raid 5

Single to RAID1 or RAIDZ to RAIDZ2 is supported (with two disks added)
not RAID1 to RAIDZ

But you can destage your QTier (provided enough poolspace on the low speed tiers), kill the fast Tier and redo it in RAIDZ.

edit
I guess it’s on the roadmap, but not implemented yet.